二硫化钼是一种二维金属硫化物,具有比表面积大、理论容量高、制备成本低等特点,是具有光明前景的锂离子电池负极材料。介绍了二硫化钼的制备方法和结构特性,归纳了其在锂离子电池负极中的具体应用,并分析了目前二硫化钼作为锂离子电池负极材料在应用中存在的问题。指出对二硫化钼的研究,应利用其比表面积大和多孔层状结构的特点,通过微纳化以及与其他材料复合两种途径,获得高性能锂离子电池负极材料。
[1] Liu Y,Tang D P,Zhong H X,et al.A novel MoS2/C nanocomposite as an anode material for lithium-ion batteries[J].Journal of Alloys and Compounds,2017,729:583-589.
[2] Oktaviano H S,Yamada K,Waki K.Nano-drilled multiwalled carbon nanotubes:characterizations and application for LIB anode materials[J].Journal of Materials Chemistry,2012,22(48):25167-25173.
[3] Cai J X,Li Z P,Li W,et al.Synthesis and electrochemical performance of Fe2O3 nanofibers as anode materials for LIBs[J].Journal of Inorganic Materials,2018,33(3):301-306.
[4] Lee W W,Lee J M.Novel synthesis of high performance anode materials for lithium-ion batteries (LIBs)[J].Journal of Materials Chemistry A,2014,2(6):1589-1626.
[5] Osaka T,Nara H,Momma T,et al.New Si-O-C composite film anode materials for LIB by electrodeposition[J].Journal of Materials Chemistry A,2014,2(4):883-896.
[6] Novoselov K S,Morozov S V,Mohinddin T M G,et al.Electronic properties of graphene[J].Physica Status Solidi B,2007,244(11):4106-4111.
[7] Tian Y,An Y L,Feng J.Flexible and freestanding silicon/MXene composite papers for high-performance lithium-ion batteries[J].ACS Applied Materials & Interfaces,2019,11(10):10004-10011.
[8] Liu W L,Zhi H Q,Yu X B.Recent progress in phosphorus based anode materials for lithium/sodium ion batteries[J].Energy Storage Mater,2019,16:290-322.
[9] Wang H,Li X,Baker-Fales M,et al.3D graphene-based anode materials for Li-ion batteries[J].Current Opinion in Chemical Engineering,2016,13:124-132.
[10] Shu H B,Li F,Hu C L,et al.The capacity fading mechanism and improvement of cycling stability in MoS2-based anode materials for lithium-ion batteries[J].Nanoscale,2016,8(5):2918-2926.
[11] Zhao B,Wang Z X,Gao Y,et al.Hydrothermal synthesis of layer-controlled MoS2/graphene composite aerogels for lithium-ion battery anode materials[J].Applied Surface Science,2016,390:209-215.
[12] 马浩,杨瑞霞,李春静.层状二硫化钼材料的制备和应用进展[J].材料导报,2017,31(3):7-14.
[13] Zhao H,Wu H,Wu J,et al.Preparation of MoS2/WS2 nanosheets by liquid phase exfoliation with assistance of epigallocatechin gallate and study as an additive for high-performance lithium-sulfur batteries[J].Journal of Colloid and Interface Science,2019,552:554-562.
[14] Adilbekova B,Lin Y,Yengel E,et al.Liquid phase exfoliation of MoS2 and WS2 in aqueous ammonia and their application in highly efficient organic solar cells[J].Journal of Materials Chemistry C,2020,8(15):5259-5264.
[15] Zhan Y,Liu Z,Nakmaei S,et al.Large-area vapor-phase growth and characterization of MoS2 atomic layers on a SiO2 substrate[J].Small,2012,8(7):966-971.
[16] Zhu J,Xu H,Zou G,et al.MoS2-OH bilayer-mediated growth of inch-sized monolayer MoS2 on arbitrary substrates[J].Journal of the American Chemical Society,2019,141(13):5392-5401.
[17] Qu M,Hou J,Liang T,et al.Preparation and interfacial properties of ultralow concentrations of amphiphilic molybdenum disulfide nanosheets[J].Industrial & Engineering Chemistry Research,2020,59(19):9066-9075.
[18] 翟英娇,李金华,楚学影,等.纳米结构二硫化钼的制备及其应用[J].无机材料学报,2015,30(9):897-905.
[19] Shi Y M,Zhou W,Lu A Y,et al.Epitaxy of MoS2 layers using graphene as growth templates[J].Nano Letters,2012,12(6):2784-2791.
[20] Mak K F,Lee C,Hong J,et al.Atomically thin MoS2:a new direct-gap semiconductor[J].Physical Review Letters,2010,105(13):1368051-1368054.
[21] Huang J,Wei Z,Liao J,et al.Molybdenum and tungsten chalcogenides for lithium/sodium-ion batteries:beyond MoS2[J].Journal of Energy Chemistry,2019,33:100-124.
[22] Kumar D P,Hong S,Reddy D A,et al.Noble metal-free ultrathin MoS2 nanosheet-decorated CdS nanorods as an efficient photocatalyst for spectacular hydrogen evolution under solar light irradiation[J].Journal of Materials Chemistry A,2016,4(47):18551-18558.
[23] 张雪倩,侯之国,敖怀生,等.二硫化钼花状纳米颗粒作为高性能锂离子电池负极材料的研究[J].中国科技论文,2017,12(16):1902-1906.
[24] Wang S Q,Li G H,Du G D,et al.Hydrothermal synthsis of molybdenum disulfide for lithium ion battery applications[J].Chinese Journal of Chemical Engineering,2010,18(6):910-913.
[25] Mou Y P,Wang C,Zhan L,et al.Synthesis and electrochemical performance of a spherical flower-like MoS2/graphene anode material for lithium ion batteries[J].New Carbon Mater,2016,31(6):609-614.
[26] Wang J G,Liu H,Zhou R,et al.Onion-like nanospheres organized by carbon encapsulated few-layer MoS2 nanosheets with enhanced lithium storage performance[J].Journal of Power Sources,2019,413:327-333.
[27] Ren J,Ren R P,Lv Y K.A flexible 3D graphene@CNT@MoS2 hybrid foam anode for high-performance lithium-ion battery[J].Chemical Engineering Journal,2018,353:419-424.
[28] Lingappan N,Kang D J.Molybdenum disulfide nanosheets interconnected nitrogen-doped reduced graphene oxide hydrogel:a high-performance heterostructure for lithium-ion batteries[J].Electrochimica Acta,2016,193:128-136.
[29] Zhang X,Huang L,Zeng P,et al.Hierarchical MoS2 anchored on core-shell Si@C with increased active-sites and charge transfer for superior cycling and rate capability in lithium-ion batteries[J].Chemical Engineering Journal,2019,357:625-632.
基金资助
国家自然科学基金(41807235)